Advanced nanotechnologies for efficient arsenic decontamination remain largely underdeveloped. The most abundant inorganic arsenic species are neutrally-charged arsenate, As(III), and negatively-charged arsenite, As(V). Compared with As(V), As(III) is 60 times more toxic and more difficult to remove due to high mobility. Herein, an electrochemical filtration system was rationally designed for one-step As(III) decontamination. The key to this technology is a functional electroactive carbon nanotube (CNT) filter functionalized with sea urchin-like FeOOH. With the assistance of electric field, CNT-FeOOH anodic filter can in situ transform As(III) to less toxic As(V) while passing through. Then, as-produced As(V) could be effectively sequestrated by FeOOH. The sufficient exposed sorption sites, flow-through design, and filter's electrochemical reactivity synergistically guaranteed a rapid arsenic removal kinetic. The underlying working mechanism was unveiled based on systematic experimental investigations and theoretical calculations. The system efficacy can be adapted across a wide pH range and environmental matrixes. Exhausted CNT-FeOOH filters could be effectively regenerated by chemical washing with diluted NaOH solution. Outcomes of the present study are dedicated to provide a straightforward and effective strategy by integrating electrochemistry, nanotechnology, and membrane separation for the removal of arsenic and other similar heavy metals from water bodies.Environmentally sound disposal of hyperaccumulator harvests is of critical importance to industrialization of phytoremediation. Herein, transformation behaviors and environmental risk of heavy metals were comprehensively examined during subcritical hydrothermal liquefaction of Sedum plumbizincicola. It is concluded that low temperature liquefaction favored resource recovery of heavy oil and hydrochars in terms of higher energy density, improved carbon sequestration and less energy consumption. Heavy metals were mainly distributed into hydrochars and water soluble phase with less than 10% in heavy oil. All metal elements except As could be accumulated in hydrochars by extending reaction time, whereas more than 96% of As was redistributed into water soluble phase. Prolonged liquefaction time facilitated immobilization of Cd, Cr and As in hydrochars, but fast liquefaction favored Pb stabilization. https://www.selleckchem.com/products/caerulein.html Liquefaction significantly reduced environmental risk level of Cd, Zn and As, but may mobilize Pb and Mn, especially for Mn to very high risk level at 240 ºC. High temperature with long reaction time tended to inhibit leaching rate of Mn, whereas low liquefaction temperature with short reaction time prevented the leaching of Zn and As from hydrochars. Overall, these findings are essential for downstream upgrading of heavy oil and metals recovery from hydrochars.Iodine compounds that may be released in case of severe nuclear accident will have important radiotoxicity if they are disseminated in air. One of the most important iodine species is CsI that is deposited on the surfaces of the reactor coolant system. However, depending on the conditions, CsI can volatilize or react with oxidants to produce I2(g). Theoretical and experimental studies demonstrate that the oxidation of iodide depends on the temperature and in the presence of oxidants in the gas. It is also slightly influenced by the crystallinity of the CsI particles and the nature of the support. In case of a high temperature deposition, the iodine release started at temperature lower than 300 °C. For the CsI vapour and aerosol depositions, the iodine is detected only at temperature above 450 °C and become very important above 550 °C.Polycyclic aromatic hydrocarbons (PAHs) are ubiquitous and harmful contaminants, which can be degraded aerobically. However, the persistence of PAHs in anoxic environments indicates that anaerobic biodegradation of PAHs should also be investigated. Pure-culture and biotransformation processes for anaerobic phenanthrene biodegradation with sulfate as a terminal electron acceptor remains in its infancy. In this study, we investigated anaerobic biodegradation of PAHs by PheS2, an isolated phenanthrene-utilizing sulfate-reducer, using phenanthrene as a model compound. PheS2 was phylogenetically closely related to Geobacter sulfurreducens and reduced sulfate to sulfide during anaerobic phenanthrene biodegradation. Phenanthrene biodegradation processes were detected using gas chromatography-mass spectrometry, genome, and reverse transcription quantitative PCR analyses. Carboxylation was the initial step of anaerobic phenanthrene biodegradation based upon detection of 2- and 4-phenanthroic acid, its isotopically labeled analogs when using 13C-labeled bicarbonate and fully deuterated-phenanthrene (C14D10), and genes encoding enzymes putatively involved in the biodegradation. Further, ring-system reducing and cleavage occurred, and substituted benzene series and cyclohexane derivatives were detected in downstream biotransformation metabolites. Additionally, PheS2 can degrade benzene, naphthalene, anthracene, and benz[a]anthracene, but not pyrene and benz[a]pyrene. This study describes the isolation of an anaerobic phenanthrene-degrading sulfate-reducer, the first pure-culture evidence of phenanthrene biotransformation processes with sulfate as an electron acceptor.Ordinary Portland cement (OPC) clinker mainly consist four minerals, tricalcium silicate (C3S), dicalcium silicate (C2S,), tricalcium aluminate (C3A), and tetracalcium aluminoferrite (C4AF). To learn the doping behaviors of Zn in OPC clinker, a series of samples were prepared by calcinating the mixtures of CaCO3, SiO2, Al2O3, Fe2O3, and ZnO. Our results from energy-dispersive spectroscopy, X-ray diffraction and density functional theoretical simulations show that a small amount of ZnO enter C3S and C2S by replacing Ca ions while most incorporate into C4AF by substituting Fe atoms, resulting in a decrease of C3A in OPC as dosage increases. Further analyses from partial density of states and distributions of bond order-bond length indicate that the doping preference can be ascribed to the similar electron contributions and small structure distortions between host and guest ions. Unlike the strong Fe?O bond, the newly formed Zn?O is much weaker. The weak Zn?O may be responsible for the limited solubility of Zn in C4AF.